Measurements and correlation of high-pressure densities of imidazolium-based ionic liquids

TitleMeasurements and correlation of high-pressure densities of imidazolium-based ionic liquids
Publication TypeJournal Article
Year of Publication2008
AuthorsTome, LIN, Coutinho, JAP, Gardas, RL
Secondary AuthorsCarvalho, PJ, Freire, MG, Ferreira, AGM
Tertiary AuthorsMarrucho, IM, Fonseca, IMA
JournalJOURNAL OF CHEMICAL AND ENGINEERING DATA
Volume53
Pagination1914-1921
Type of ArticleResearch Article
ISSN0021-9568
Keywordsionic liquid
Abstract{In the present work, experimental density measurements are reported along with the derived thermodynamic properties, such as the isothermal compressibility (K-T), the isobaric expansivity (alpha(p)), and the thermal pressure coefficient (gamma(upsilon),) for imidazolium-based ionic liquids (ILs), namely, 1-ethyl-3-methylimidazolium methylsulfate {[}C(2)mim]{[}MeSO4], 1-ethyl-3-methylimidazolium ethylsulfate {[}C(2)mim]{[}EtSO4], 1,3-diethylimidazolium bis(trifluoromethylsulfonyl)imide {[}C2mim]{[}Tf2N], and 1-decyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide {[}C(10)mim]{[}Tf2N] in the pressure (0.10 < P/MPa < 35.00) and temperature (293.15 < T/K < 393.15) domains. It is shown that experimental densities are in good agreement with the predicted densities obtained by the Gardas and Coutinho method and the correlation using the Tait equation and Sanchez-Lacombe equation of state.}
DOI10.1021/je800316b