Course Information

Found 2 records with CourseId:10144 in academic section database. Picking the first.

Course Name: CY5011 : Transition Metal and Organometallic Chemistry

Description: Transition Metal Chemistry Structure, bonding and properties of transition metal ligand complexes ? ligand, coordination, geometry, coordination number, isomerism (recapitulation); HSAB concept, thermodynamic stability, successive and overall stability constants, Irving-William series, chelate and macrocyclic effect. Theories of bonding - VBT, CFT and their limitations; d-orbital splitting in octahedral, JT-distorted octahedral, square planar, square pyramidal, trigonal bipyramidal, and tetrahedral complexes; CFSE for d1 to d10 systems, pairing energy, low-spin and high-spin complexes and magnetic properties; LFT, and molecular orbital (MO) theory of selected octahedral and tetrahedral complexes. Electronic Spectra - UV-Vis, charge transfer, colors, intensities and origin of spectra, interpretation, term symbols and splitting of terms in free atoms, selection rules for electronic transitions, Orgel and Tanabe-Sugano diagram, calculation of Dq, B, C, Nephelauxetic ratio. Reaction mechanisms - substitution r

Slot: A

RoomNo: CB 310

Instructor: Murthy N N

Period: JUL-NOV 2013

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